Technical chemistry, reagents

Diphenylamine

Article ID
CT-1268

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Description and specifications

Diphenylamine (DPA) is an organic compound, an aromatic amine with the formula (C₆H₅)₂NH. It is a colorless or slightly yellowish crystalline substance with a faint odor, poorly soluble in water but soluble in organic solvents.

Appearance Fine crystals, light gray to light yellow
DPA Content % ≥99.8
Low-boiling impurities % ≤0.2
High-boiling impurities % ≤0.3
Aniline content % ≤0.05
Freezing point ℃ ≥52.50
Aqueous extract reaction Neutral
Moisture content % ≤0.2
Insoluble matter % ≤0.05

Production of Diphenylamine

Diphenylamine is produced by several methods:

  1. Reaction of aniline with chlorobenzene: Aniline reacts with chlorobenzene at high temperature with catalysts.
  2. Reduction of nitrobenzene: Nitrobenzene is reduced with hydrogen and catalysts.
  3. Reaction of phenol with aniline: Phenol and aniline interact with acid catalysts.

Applications of Diphenylamine

Diphenylamine is used in:

  • Stabilizers: For explosives and polymers.
  • Dye production: As an intermediate for the textile industry.
  • Antioxidant: For lubricating oils and fuels.
  • Metal protection: In corrosion inhibitors.
  • Agriculture: To protect fruits from spoilage.
  • Laboratory research: For the detection of nitrates and nitrites.

Safety and Environment

Diphenylamine is toxic! Protective equipment must be used and contact with skin should be avoided. Disposal must comply with environmental regulations.

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